There are two main types of kilns to produce cement: the Vertical Shaft Kiln and the Rotary Kiln. The Vertical Shaft Kiln or VSK is probably the first type of kiln that was used and it can be traced back to the 5th century A.C. in Greece, when they were used for limestone calcining (Reiter, AC, 11/1997, p. 23). In the 20th century, they have been largely replaced by rotary kilns, which were implemented for the first time in 1880. However, in several countries such as China and India, many of these kilns are still operating (4000 units in China in 2005) and even, some companies still offer this technology for sale.
However, the Chinese government expects to close all mechanized shaft kilns by 2020 and that only 10% of the optimized vertical kilns keep operating. (Karstensen, UNIDO, 2006, p. 13). Henan Zhengzhou Mining Machinery Co., Ltd offers only rotary kilns with preheater tower, with or without calciner.
The theoretical heat of reaction required to make high-calcium lime is around 3.15 MJ per kg of lime, so the batch kilns were only around 20% efficient. The key to development in efficiency was the invention of continuous kilns, avoiding the wasteful heat-up and cool-down cycles of the batch kilns. The first were simple shaft kilns, similar in construction to blast furnaces. These are counter-current shaft kilns. Modern variants include regenerative and annular kilns. Output is usually in the range 100–500 tonnes per day.
The fuel is injected part-way up the shaft, producing maximum temperature at this point. The fresh feed fed in at the top is first dried then heated to 800 °C, where de-carbonation begins, and proceeds progressively faster as the temperature rises. Below the burner, the hot lime transfers heat to, and is cooled by, the combustion air. A mechanical grate withdraws the lime at the bottom. A fan draws the gases through the kiln, and the level in the kiln is kept constant by adding feed through an airlock. As with batch kilns, only large, graded stone can be used, in order to ensure uniform gas-flows through the charge. The degree of burning can be adjusted by changing the rate of withdrawal of lime. Heat consumption as low as 4 MJ/kg is possible, but 4.5 to 5 MJ/kg is more typical. Due to temperature peak at the burners up to 1200 °C in a shaft kiln conditions are ideal to produce medium and hard burned lime.
2. Rotary kilns
Rotary kilns started to be used for lime manufacture at the start of the 20th century and now account for a large proportion of new installations if energy costs are less important. The early use of simple rotary kilns had the advantages that a much wider range of limestone size could be used, from fines upwards, and undesirable elements such as sulfur can be removed. On the other hand, fuel consumption was relatively high because of poor heat exchange compared with shaft kilns, leading to excessive heat loss in exhaust gases. Old fashioned "long" rotary kilns operate at 7 to 10 MJ/kg. Modern installations partially overcome this disadvantage by adding a preheater, which has the same good solids/gas contact as a shaft kiln, but fuel consumption is still somewhat higher, typically in range of 4.5 to 6 MJ/kg. In the design shown, a circle of shafts (typically 8–15) is arranged around the kiln riser duct. Hot limestone is discharged from the shafts in sequence, by the action of a hydraulic "pusher plate". Kilns of 1000 tonnes per day output are typical. The rotary kiln is the most flexible of any lime kilns able to produce soft, medium, or hard burned as well as dead-burned lime.
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